
Breakup on three pathways. A hydronium ion captures an electron and can then split into different combinations of fragments. The relative yields of the three pathways are shown as measured for the heavy hydronium ion D3O+. The capture produces the unstable radical D3O with the captured electron in a weakly bound (Rydberg) state.
The research appears in the journal Physical Review Letters.
In comets as well as in interstellar clouds, the precursor molecule of water is the positively charged hydronium ion H3O+. This molecular ion can be detected from earth by telescopes. In the cosmic clouds negatively charged electrons are also present, causing frequent collisions. In those the hydronium ion converts to the neutral instable radical H3O, which rapidly decays. "For this break-up reaction, nature offers three choices," describes Andreas Wolf, forming either H2O plus H, or OH plus H2, or OH plus two H atoms. Present research tries to determine the yields of these production channels, including that of water.












