The deep interior of Neptune, Uranus and Earth may contain some solid ice.
Through first-principle molecular dynamics simulations, Lawrence Livermore National Laboratory scientists, together with University of California, Davis collaborators, used a two-phase approach to determine the melting temperature of ice VII (a high-pressure phase of ice) in pressures ranging from 100,000 to 500,000 atmospheres.
|
| ©Visualization by Eric Schwegler/LLNL
|
| A snapshot from a first-principle molecular dynamics simulation of ice-VII (on the right) in contact with liquid water (on the left). As the simulation progresses the position of the solid-liquid interface can be monitored and used to accurately determine the location of the melting temperature of water under high pressure conditions.
|
For pressures between 100,000 and 400,000 atmospheres, the team, led by Eric Schwegler, found that ice melts as a molecular solid (similar to how ice melts in a cold drink). But in pressures above 450,000 atmospheres, there is a sharp increase in the slope of the melting curve due to molecular disassociation and proton diffusion in the solid, prior to melting, which is typically referred to as a superionic solid phase.
"The sharp increase in the melting curves slope opens up the possibility that water exists as a solid in the deep interior of planets such as Neptune, Uranus and Earth," Schwegler said.