© Carnegie Institution
New experiments and supercomputer computations discovered that iron oxide undergoes a new kind of transition under deep Earth conditions. Iron oxide, FeO, is a component of the second most abundant mineral at Earth's lower mantle, ferropericlase. The finding, published in an upcoming issue of Physical Review Letters, could alter our understanding of deep Earth dynamics and the behavior of the protective magnetic field, which shields our planet from harmful cosmic rays.
Ferropericlase contains both magnesium and iron oxide. To imitate the extreme conditions in the lab, the team including coauthor Ronald Cohen of Carnegie's Geophysical Laboratory, studied the electrical conductivity of iron oxide to pressures and temperatures up to 1.4 million times atmospheric pressure and 4000°F - on par with conditions at the core-mantle boundary. They also used a new computational method that uses only fundamental physics to model the complex many-body interactions among electrons. The theory and experiments both predict a new kind of metallization in FeO.
Compounds typically undergo structural, chemical, electronic, and other changes under these extremes. Contrary to previous thought, the iron oxide went from an insulating (non-electrical conducting) state to become a highly conducting metal at 690,000 atmospheres and 3000°F, but without a change to its structure. Previous studies had assumed that metallization in FeO was associated with a change in its crystal structure. This result means that iron oxide can be both an insulator and a metal depending on temperature and pressure conditions.
